WAEC 2018 Chemistry Practical Expo Answer Solution

WAEC 2018 Chemistry Practical Expo Answer Solution | Waec 2018 Chemistry Practical Answer

Chemistry 3 (Practical) (Alternative A) 09.30am – 11.30am (1st Set)
Chemistry 3 (Practical) (Alternative A) 12.00pm – 2.00pm (2nd Set)

NOTE:
Tita means θ

^ means Raise to power

Pie means π

/ (means) division or divide

2 whole no 3/4 means 2¾
* means
multiplication (×)

Sqr root means √

Proportional means

1)
Tabulate
Burette reading|Final burette reading
(cm^3)|Initial burette reading (cm^3)|
Volume of acid used(cm^3)|
Rough- 24.10,0.00,24.10
First- 23.80, 0.00, 23.80
Second- 23.75, 0.00, 23.70
Third- 23.75, 0.00, 23.75
Average volume of A used = 23.80 + 23.70 + 23.75cm^3/3
=23.75cm^3

1bi)
CAVA/CcVc=2/1
Cc=CAVA/2VC
=0.100*23.75Moldm^-3/2*25.00
=0.0475moldm^-3
amount of A used = 0.100x VA/1000=0.100*23.75/1000 =0.00237
2moles Of A = 1mole of C
0.002375mol of A = 0.002375mol/2
100cm^3 of C contain 0.00237*100mol/2*25 =0
1000cm3ofCcontained0.002375x1000mol
2×25
=0.0475mol
concentration of C in moldm-3 =0.0475moldm-3

1bii)
Molar mass of Bing mol-1:
Molar mass of Na2CO3.yH2O=mass concentration of Bingdm-3
molar concentration of Binmoldm-3
=13.6gdm-3
0.0475moldm-3
=286gmol-1

1biii)
Molar mass of Na2CO3 =[(2×23)+12+(16×3)]=106gmol-1
Mass of anhydrous Na2CO3=106×0.0475gdm-3
=5.035gdm-3
Mass of water=13.6-5.035gdm-3
=8.565gdm-3
Mass of Na2CO3 =Molar mass of Na2CO3
Mass of water y×Molar mass of water
5.035=106
8.565 18y
y =106×8.565
5.035×18
=10

==================================

(2)Tabulate
Test
(a)(i)Fn+H2O,then

filter

Observation
White residue and blue
filtrate was observed

Inference
Fn is a mixture of

soluble and insoluble

salts

Test
(ii)Filtrate+NaOH(aq)in

drops,then in excess
Observation
A blue gelatinous
precipitate which is
insoluble in excess
NaOH(aq)was formed

Inference
Cu2+present

Test
(iii)Filtrate+NH3(aq)in

drops,then in excess

Observation
A pale blue gelatinous
precipitate was
formed. The precipitate

dissolves or is soluble

in excess NH3(aq)to give
a deep blue solution

Inference
Cu2+confirmed

Test
(iv)Filtrate+dil.HNO3

+AgNO3(aq)

Observation
No visible reaction
White precipitate

formed

Inference
Cl-present

Test
+NH3(aq)in excess

Observation
Precipitatedissolvedin

excessNH3(aq)

Inference
Cl-confirmed

=====================≠=====

3a)
I)Desiccator- use for preserving moisture sensitive items

ii)Volumetric flasks are used for precise dilutions and
preparation of standard solutions.

iii)Glass rod are used to mix chemicals and liquids for
laboratory purposes .

3ii)
i)Amphoteric is Al2O3

ii) Neutral oxide is H2O

3iii) Crystallization

3b.
1. hno3aq to cuco3 solid. a light blue solid,
precipitates is formed

2. acidified kmno4 to c2h4. c2h4 is oxidized to
ethane-1,2-
diol

3. iodine solution to a paste of unripe plantain. a
bluish-black color is produced with iodine

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